1. What's the difference between "uneasy" and "uncomfortable"? Can both be used interchangeably?

2. What's the difference between "all the time" and "at all times"? Can both be used interchangeably?

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Yes, thats right. You can be uncomfortable from anything, pain, embarrassment and so on. But uneasy is more naturally used when a SITUATION (or sometimes a person) makes you feel bad or weird.

Examples for uncomfortable:

A: This chair is too hard. Sitting on it for a long time makes me feel uncomfortable.
B: His constant staring made me feel uncomfortable.
C: This new suit costs 12000 Euros. The price makes me feel uncomfortable.

Examples for Uneasy:

D: There's something that makes me feel uneasy about this room.
E: I'm uneasy about walking across the park late at night.
F: The detective was uneasy about her explanation. Some aspects made him feel uneasy.